Search results for "Vibration–rotation spectra"
showing 2 items of 2 documents
On the Study of Resonance Interactions and Splittings in the PH3 Molecule: ν1, ν3, ν2+ν4, and 2ν4 Bands
2002
International audience; The high-resolution (0.005 cm−1) Fourier transform infrared spectrum of PH3 is recorded and analyzed in the region of the fundamental stretching bands, ν1 and ν3. The ν2 + ν4 and 2ν4 bands are taken into account also. Experimental transitions are assigned to the ν1, ν3, ν2 + ν4, and 2ν4 bands with the maximum value of quantum number J equal to 15, 15, 13, and 15, respectively. a1–a2 splittings are observed and described up to the value of quantum number K equal to 10. The analysis of a1/a2 splittings is fulfilled with a Hamiltonian model which takes into account numerous resonance interactions among all the upper vibrational states
High-resolution study of some doubly excited vibrational states of PH2D: the m1 + m2, m2 + m5, m2 + m3, and m2 + m6 bands
2004
Abstract The absorption bands ν 1 + ν 2 , ν 2 + ν 3 , and ν 2 + ν 6 of PH 2 D have been recorded for the first time using a high-resolution Bruker 120 HR interferometer, and rotationally analyzed. Some transitions belonging to the very weak band ν 2 + ν 5 and enhanced in intensity by strong interactions with the ν 1 + ν 2 band were also assigned. Sets of parameters obtained from the fit reproduce experimental line position of the bands ν 1 + ν 2 and ν 2 + ν 3 with about the experimental accuracy. The residuals of the ro-vibrational energies of the ν 2 + ν 6 band are about 10 times larger. Reasons for the poorer reproduction of the latter data are given.